Math Problem Statement

Calculate the wavelength (in nm) for the electronic transition from n = 3 to n = 5 in the hydrogen atom.

Solution

To calculate the wavelength of light for the electronic transition in a hydrogen atom from n=3n = 3 to n=5n = 5, we use the Rydberg formula:

1λ=RH(1n121n22)\frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right)

Where:

  • λ\lambda is the wavelength,
  • RHR_H is the Rydberg constant, RH=1.097×107m1R_H = 1.097 \times 10^7 \, \text{m}^{-1},
  • n1n_1 is the lower energy level (3 in this case),
  • n2n_2 is the higher energy level (5 in this case).

Step-by-step calculation:

  1. Substitute the values: 1λ=1.097×107(132152)\frac{1}{\lambda} = 1.097 \times 10^7 \left( \frac{1}{3^2} - \frac{1}{5^2} \right) 1λ=1.097×107(19125)\frac{1}{\lambda} = 1.097 \times 10^7 \left( \frac{1}{9} - \frac{1}{25} \right)

  2. Simplify the fractions: 19=0.1111,125=0.04\frac{1}{9} = 0.1111, \quad \frac{1}{25} = 0.04 19125=0.11110.04=0.0711\frac{1}{9} - \frac{1}{25} = 0.1111 - 0.04 = 0.0711

  3. Now calculate 1λ\frac{1}{\lambda}: 1λ=1.097×107×0.0711=7.801×105m1\frac{1}{\lambda} = 1.097 \times 10^7 \times 0.0711 = 7.801 \times 10^5 \, \text{m}^{-1}

  4. To find λ\lambda, take the reciprocal: λ=17.801×105m=1.282×106m\lambda = \frac{1}{7.801 \times 10^5} \, \text{m} = 1.282 \times 10^{-6} \, \text{m}

  5. Convert the wavelength to nanometers (1 m = 10910^9 nm): λ=1.282×106m×109nm/m=1282nm\lambda = 1.282 \times 10^{-6} \, \text{m} \times 10^9 \, \text{nm/m} = 1282 \, \text{nm}

Thus, the wavelength of the electronic transition from n=3n = 3 to n=5n = 5 in the hydrogen atom is 1282 nm.

Would you like more details or have any questions?

Related Questions:

  1. How does the Rydberg formula apply to other atoms beyond hydrogen?
  2. What is the significance of energy level transitions in hydrogen spectroscopy?
  3. How does the wavelength change if the transition occurs between other levels, such as n=2n = 2 and n=4n = 4?
  4. What are the visible wavelengths for transitions in the hydrogen atom?
  5. Can we calculate the energy corresponding to this wavelength?

Tip:

Remember that transitions between higher energy levels (like n=3n = 3 to n=5n = 5) typically result in wavelengths in the infrared region, while transitions involving lower levels might be in the visible or ultraviolet range.

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Math Problem Analysis

Mathematical Concepts

Atomic Physics
Spectroscopy
Algebra

Formulas

Rydberg Formula: 1/λ = RH(1/n1^2 - 1/n2^2)

Theorems

Rydberg Formula for Hydrogen Spectrum

Suitable Grade Level

Grades 10-12, Undergraduate