Math Problem Statement

      Calculate the wavelength of light produced if an electron moves from 

n=5 state to n=4 state of an electron in a hydrogen atom. Express your answer to three significant figures and include the appropriate units.

Solution

To calculate the wavelength of light emitted when an electron moves from n=5n = 5 to n=4n = 4 in a hydrogen atom, we can use the Rydberg formula for hydrogen:

1λ=RH(1n121n22)\frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right)

where:

  • λ\lambda is the wavelength of the emitted light,
  • RHR_H is the Rydberg constant for hydrogen, RH=1.097×107m1R_H = 1.097 \times 10^7 \, \text{m}^{-1},
  • n1n_1 is the lower energy level (in this case n1=4n_1 = 4),
  • n2n_2 is the higher energy level (in this case n2=5n_2 = 5).

Step-by-step solution:

  1. Substitute the values into the Rydberg formula: 1λ=1.097×107(142152)\frac{1}{\lambda} = 1.097 \times 10^7 \left( \frac{1}{4^2} - \frac{1}{5^2} \right)

  2. Calculate the terms inside the parentheses: 142=116=0.0625\frac{1}{4^2} = \frac{1}{16} = 0.0625 152=125=0.04\frac{1}{5^2} = \frac{1}{25} = 0.04 116125=0.06250.04=0.0225\frac{1}{16} - \frac{1}{25} = 0.0625 - 0.04 = 0.0225

  3. Now substitute this difference into the equation: 1λ=1.097×107×0.0225=2.46825×105m1\frac{1}{\lambda} = 1.097 \times 10^7 \times 0.0225 = 2.46825 \times 10^5 \, \text{m}^{-1}

  4. Finally, take the reciprocal to find λ\lambda: λ=12.46825×105=4.052×106m=4052nm\lambda = \frac{1}{2.46825 \times 10^5} = 4.052 \times 10^{-6} \, \text{m} = 4052 \, \text{nm}

Answer:

The wavelength of light produced is 4050nm\mathbf{4050 \, \text{nm}} (rounded to three significant figures).

Would you like more details or further clarifications?

Here are 5 related questions:

  1. What is the Rydberg constant, and why is it important in hydrogen spectrum calculations?
  2. How does the energy difference between electron levels relate to the wavelength of emitted light?
  3. Why do different transitions in hydrogen produce different wavelengths?
  4. How does the wavelength of light change with higher nn-level transitions in hydrogen?
  5. What other series of transitions exist in the hydrogen atom besides this one?

Tip: Transitions to the lowest energy levels (like n=1n=1) produce light in the ultraviolet range, while transitions between higher levels (e.g., n=5n=5 to n=4n=4) produce infrared light.

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Math Problem Analysis

Mathematical Concepts

Quantum Mechanics
Spectral Lines
Energy Levels
Wavelength Calculation

Formulas

Rydberg formula: 1/λ = R_H * (1/n_1^2 - 1/n_2^2)

Theorems

Rydberg's Theorem: Used to calculate the wavelength of spectral lines in hydrogen atoms

Suitable Grade Level

High School (Grades 10-12), Introductory College Physics