Math Problem Statement

What is the solubility of MgCO3 in water? (Ksp of MgCO3 is 3.5 x 10^-8)

Solution

To find the solubility of magnesium carbonate (MgCO₃) in water, we use the solubility product constant (Ksp). The Ksp for MgCO₃ is given as 3.5×1083.5 \times 10^{-8}.

The dissolution of MgCO₃ in water is represented by the following equilibrium reaction:

MgCO3(s)Mg2+(aq)+CO32(aq)\text{MgCO}_3 (s) \rightleftharpoons \text{Mg}^{2+} (aq) + \text{CO}_3^{2-} (aq)

Let the solubility of MgCO₃ in mol/L be ss. This means that at equilibrium, the concentration of Mg2+\text{Mg}^{2+} ions and CO32\text{CO}_3^{2-} ions will both be equal to ss, since for every mole of MgCO₃ that dissolves, one mole of each ion is produced.

The Ksp expression is:

[ K_{sp} = [\text{Mg}^{2+}][\text{CO}_3^{2-}] ]

Since both concentrations are equal to ss, we can substitute them into the expression:

Ksp=s×s=s2K_{sp} = s \times s = s^2

Now, solving for ss:

3.5×108=s23.5 \times 10^{-8} = s^2

s=3.5×108s = \sqrt{3.5 \times 10^{-8}}

s=5.92×104mol/Ls = 5.92 \times 10^{-4} \, \text{mol/L}

Thus, the solubility of MgCO₃ in water is approximately 5.92×104mol/L5.92 \times 10^{-4} \, \text{mol/L}.

Would you like further details or have any questions?

Here are 5 related questions to further explore this topic:

  1. How does the solubility of MgCO₃ change in the presence of common ions?
  2. What effect does temperature have on the solubility of MgCO₃?
  3. How would you calculate the solubility of MgCO₃ in a solution with pH = 7?
  4. How is the solubility product related to the common ion effect?
  5. Can you calculate the molar mass of MgCO₃ and convert the solubility into grams per liter?

Tip: When calculating solubility, always double-check your Ksp expression to ensure you're accounting for the correct ion concentrations.

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Math Problem Analysis

Mathematical Concepts

Equilibrium Chemistry
Solubility Product (Ksp)
Algebra

Formulas

Ksp = [Mg²⁺][CO₃²⁻]
Ksp = s²
s = √Ksp

Theorems

Solubility Product Theorem

Suitable Grade Level

Grades 10-12