Math Problem Statement

A certain quantity of gas is heated at constant pressure from 35°C to 185°C. Estimate the amount of heat transferred, ideal work done, change in internal energy, when initial volume of gas is 0.6 m³.

Solution

To solve this problem, we will use the ideal gas laws and thermodynamic relations for an ideal gas heated at constant pressure. Let's break it down into three main parts:

  1. Heat Transferred (QQ): For an ideal gas at constant pressure, the amount of heat transferred can be calculated using: Q=nCpΔTQ = n C_p \Delta T where:

    • nn is the number of moles of gas,
    • CpC_p is the specific heat capacity at constant pressure,
    • ΔT\Delta T is the change in temperature.

    However, we need to find nn and we will use the formula: n=PVRTn = \frac{PV}{RT} where:

    • PP is the pressure,
    • VV is the initial volume,
    • RR is the universal gas constant =8.314J/(mol\cdotpK)= 8.314 \, \text{J/(mol·K)},
    • TT is the initial temperature in Kelvin.
  2. Work Done by the Gas (WW): For an isobaric process (constant pressure), the work done by the gas is given by: W=PΔVW = P \Delta V or W=nRΔTW = nR \Delta T

  3. Change in Internal Energy (ΔU\Delta U): For an ideal gas, the change in internal energy is given by: ΔU=nCvΔT\Delta U = n C_v \Delta T where CvC_v is the specific heat capacity at constant volume.

Since CpCv=RC_p - C_v = R, we can use the relationship: ΔU=QW\Delta U = Q - W

Let's calculate step-by-step.

Step 1: Convert Temperatures to Kelvin

T1=35C+273.15=308.15KT_1 = 35^\circ C + 273.15 = 308.15 \, K T2=185C+273.15=458.15KT_2 = 185^\circ C + 273.15 = 458.15 \, K

Step 2: Find the Number of Moles (nn)

To calculate nn, we need the pressure PP. Since it is not given, we will assume standard atmospheric pressure (1 atm = 101325 Pa).

n=PVRT1=101325×0.68.314×308.15n = \frac{PV}{RT_1} = \frac{101325 \times 0.6}{8.314 \times 308.15}

Let's compute nn.

Step 3: Calculate Heat Transferred (QQ)

Once we have nn, we can calculate QQ using: Q=nCpΔTQ = n C_p \Delta T For a diatomic ideal gas (e.g., air), Cp29.1J/(mol\cdotpK)C_p \approx 29.1 \, \text{J/(mol·K)}.

ΔT=T2T1=458.15308.15=150K\Delta T = T_2 - T_1 = 458.15 - 308.15 = 150 \, K

Step 4: Calculate Work Done (WW)

W=nRΔTW = nR \Delta T

Step 5: Calculate Change in Internal Energy (ΔU\Delta U)

ΔU=QW\Delta U = Q - W

Let's perform the calculations.Here are the results for the thermodynamic quantities:

  1. Number of moles (nn): 23.73mol23.73 \, \text{mol}
  2. Heat Transferred (QQ): 103,581J103,581 \, \text{J} (or 103.6kJ103.6 \, \text{kJ})
  3. Work Done by the Gas (WW): 29,594J29,594 \, \text{J} (or 29.6kJ29.6 \, \text{kJ})
  4. Change in Internal Energy (ΔU\Delta U): 73,987J73,987 \, \text{J} (or 74.0kJ74.0 \, \text{kJ})

Summary

  • The heat transferred to the gas during heating is approximately 103.6kJ103.6 \, \text{kJ}.
  • The ideal work done by the gas due to expansion is around 29.6kJ29.6 \, \text{kJ}.
  • The change in internal energy, which accounts for both the work done and the heat added, is about 74.0kJ74.0 \, \text{kJ}.

Would you like more details or have any questions?

Related Questions:

  1. What is the relationship between CpC_p and CvC_v for an ideal gas?
  2. How does the specific heat capacity affect the heat transferred to a gas?
  3. What would be the impact on work done if the gas was monatomic instead of diatomic?
  4. How is the first law of thermodynamics applied in this problem?
  5. How can these calculations be modified for non-ideal gases?

Tip:

Remember that for an ideal gas, the internal energy change depends only on the temperature change, not on the volume or pressure changes.

Ask a new question for Free

By Image

Drop file here or Click Here to upload

Math Problem Analysis

Mathematical Concepts

Thermodynamics
Ideal Gas Law
Heat Transfer
Work and Energy

Formulas

Q = n C_p ΔT
n = PV/RT
W = nR ΔT
ΔU = Q - W

Theorems

First Law of Thermodynamics

Suitable Grade Level

College Level (Thermodynamics or Physics Course)