Math Problem Statement

A mass of 12kg gas expands within a flexible container so that pv relationship is of the form pvl. 2= constant. The Initial pressure is 1600kPa and the initial volume is 2 m3.The final pressure is 20 kPa. If specific internal energy of the gas decreases by 80kJ/kg.Find the heat transfer in magnitude and direction.

Solution

To solve this, let's break down the information and use the first law of thermodynamics for a closed system. Given:

  • Initial pressure, P1=1600kPaP_1 = 1600 \, \text{kPa}
  • Initial volume, V1=2m3V_1 = 2 \, \text{m}^3
  • Final pressure, P2=20kPaP_2 = 20 \, \text{kPa}
  • Mass of gas, m=12kgm = 12 \, \text{kg}
  • Specific internal energy change, Δu=80kJ/kg\Delta u = -80 \, \text{kJ/kg} (decrease, so it's negative)

We’re asked to find the heat transfer, QQ.

Step 1: Determine the Final Volume V2V_2

The given relation is: PV1.2=constantP V^{1.2} = \text{constant}

Using the initial state: P1V11.2=P2V21.2P_1 V_1^{1.2} = P_2 V_2^{1.2} Substitute the known values: 1600×21.2=20×V21.21600 \times 2^{1.2} = 20 \times V_2^{1.2}

First, calculate 21.22^{1.2}: 21.22.2972^{1.2} \approx 2.297

Then substitute: 1600×2.297=20×V21.21600 \times 2.297 = 20 \times V_2^{1.2} V21.2=1600×2.29720=183.76V_2^{1.2} = \frac{1600 \times 2.297}{20} = 183.76

Now, solve for V2V_2: V2=(183.76)11.280.18m3V_2 = (183.76)^{\frac{1}{1.2}} \approx 80.18 \, \text{m}^3

Step 2: Calculate Work Done WW Using the PVPV Relationship

The work done WW for a polytropic process PVn=constantPV^n = \text{constant} is given by: W=P2V2P1V11nW = \frac{P_2 V_2 - P_1 V_1}{1 - n} where n=1.2n = 1.2.

Substitute the values: W=(20×80.18)(1600×2)11.2W = \frac{(20 \times 80.18) - (1600 \times 2)}{1 - 1.2} Calculate each term: P2V2=20×80.18=1603.6kJP_2 V_2 = 20 \times 80.18 = 1603.6 \, \text{kJ} P1V1=1600×2=3200kJP_1 V_1 = 1600 \times 2 = 3200 \, \text{kJ}

Thus: W=1603.632000.2=1596.40.2=7982kJW = \frac{1603.6 - 3200}{-0.2} = \frac{-1596.4}{-0.2} = 7982 \, \text{kJ}

Step 3: Apply the First Law of Thermodynamics to Find QQ

The first law of thermodynamics states: Q=ΔU+WQ = \Delta U + W where ΔU\Delta U is the change in internal energy and is given by: ΔU=mΔu=12×(80)=960kJ\Delta U = m \Delta u = 12 \times (-80) = -960 \, \text{kJ}

Now substitute values into the first law: Q=960+7982=7022kJQ = -960 + 7982 = 7022 \, \text{kJ}

Conclusion

The heat transfer QQ is 7022 kJ. Since QQ is positive, heat flows into the system.


Would you like further details on any steps, or do you have any questions?


  1. How would the solution change if the final pressure was different?
  2. What would happen if the specific internal energy increased instead of decreased?
  3. How does the polytropic exponent affect work done calculations?
  4. How does this process compare with an isothermal process in terms of work done?
  5. How is heat transfer affected by mass in closed systems?

Tip: In polytropic processes, knowing the polytropic index nn can help determine how pressure and volume interact during changes.

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Math Problem Analysis

Mathematical Concepts

Thermodynamics
Polytropic Process
Energy Conservation

Formulas

Polytropic relationship: PV^n = constant
Work done in a polytropic process: W = (P2 * V2 - P1 * V1) / (1 - n)
First Law of Thermodynamics: Q = ΔU + W
Change in internal energy: ΔU = m * Δu

Theorems

First Law of Thermodynamics

Suitable Grade Level

College level or Advanced High School Physics