Let's solve the expression step-by-step:

The expression is:

$\frac{100}{4} \times (2 + 3)$

1. Calculate the expression inside the parentheses:

   $2 + 3 = 5$

2. Divide 100 by 4:

   $\frac{100}{4} = 25$

3. Multiply the result by 5:

   $25 \times 5 = 125$

So, the value of the expression $\frac{100}{4} \times (2 + 3)$ is:

$\boxed{125}$

Would you like further details or have any questions? Here are some related questions to explore:

1. How do you handle operations when there are multiple parentheses?
2. What is the difference between using parentheses and brackets in expressions?
3. How does the order of operations (PEMDAS/BODMAS) affect calculations?
4. What happens if you misinterpret the placement of multiplication and division?
5. How do parentheses affect multiplication and division?

Tip: Always resolve operations inside parentheses first, then follow the order of operations (PEMDAS/BODMAS: Parentheses, Exponents, Multiplication/Division (left to right), Addition/Subtraction (left to right)).