Math Problem Statement

What is the limiting reactant, mass of CO2 formed, and mass of excess reactant remaining in the reaction between sodium bicarbonate (NaHCO3) and citric acid (C6H8O7)? Given 300g of each reactant.

Solution

To solve the given problem, we need to address the three questions step-by-step:

Step 1: Chemical Equation and Molar Mass

The balanced chemical equation is: 3NaHCO3+H3C6H5O73CO2+3H2O+Na3C6H5O73 \text{NaHCO}_3 + \text{H}_3\text{C}_6\text{H}_5\text{O}_7 \rightarrow 3 \text{CO}_2 + 3 \text{H}_2\text{O} + \text{Na}_3\text{C}_6\text{H}_5\text{O}_7

Molar masses (approximately):

  • NaHCO3\text{NaHCO}_3: 84g/mol84 \, \text{g/mol}
  • H3C6H5O7\text{H}_3\text{C}_6\text{H}_5\text{O}_7: 192g/mol192 \, \text{g/mol}
  • CO2\text{CO}_2: 44g/mol44 \, \text{g/mol}

Step 2: Determine the Limiting Reactant

Given masses:

  • 300g300 \, \text{g} of NaHCO3\text{NaHCO}_3
  • 300g300 \, \text{g} of H3C6H5O7\text{H}_3\text{C}_6\text{H}_5\text{O}_7

Convert to moles: Moles of NaHCO3=300843.57mol\text{Moles of } \text{NaHCO}_3 = \frac{300}{84} \approx 3.57 \, \text{mol} Moles of H3C6H5O7=3001921.56mol\text{Moles of } \text{H}_3\text{C}_6\text{H}_5\text{O}_7 = \frac{300}{192} \approx 1.56 \, \text{mol}

From the balanced equation, the reaction requires:

  • 3 moles of NaHCO3\text{NaHCO}_3 for 1 mole of H3C6H5O7\text{H}_3\text{C}_6\text{H}_5\text{O}_7.

To find the limiting reactant, compare the actual mole ratio: Ratio of NaHCO3H3C6H5O7=3.571.562.29\text{Ratio of } \frac{\text{NaHCO}_3}{\text{H}_3\text{C}_6\text{H}_5\text{O}_7} = \frac{3.57}{1.56} \approx 2.29 The reaction requires a ratio of 3:1, but we have less NaHCO3\text{NaHCO}_3 than needed. Therefore, NaHCO3\text{NaHCO}_3 is the limiting reactant.


Step 3: Mass of CO2\text{CO}_2 Formed

From the balanced equation:

  • 3 moles of NaHCO3\text{NaHCO}_3 produce 3 moles of CO2\text{CO}_2.

Moles of CO2\text{CO}_2 produced: Moles of CO2=Moles of NaHCO3=3.57mol\text{Moles of } \text{CO}_2 = \text{Moles of } \text{NaHCO}_3 = 3.57 \, \text{mol}

Mass of CO2\text{CO}_2: Mass of CO2=3.57×44157.08g\text{Mass of } \text{CO}_2 = 3.57 \times 44 \approx 157.08 \, \text{g}


Step 4: Mass of Excess Reactant Remaining

Excess reactant: H3C6H5O7\text{H}_3\text{C}_6\text{H}_5\text{O}_7.

Moles of H3C6H5O7\text{H}_3\text{C}_6\text{H}_5\text{O}_7 consumed: Moles consumed=Moles of NaHCO33=3.5731.19mol\text{Moles consumed} = \frac{\text{Moles of } \text{NaHCO}_3}{3} = \frac{3.57}{3} \approx 1.19 \, \text{mol}

Moles of H3C6H5O7\text{H}_3\text{C}_6\text{H}_5\text{O}_7 remaining: Moles remaining=1.561.19=0.37mol\text{Moles remaining} = 1.56 - 1.19 = 0.37 \, \text{mol}

Mass of H3C6H5O7\text{H}_3\text{C}_6\text{H}_5\text{O}_7 remaining: Mass remaining=0.37×19271.04g\text{Mass remaining} = 0.37 \times 192 \approx 71.04 \, \text{g}


Final Answers:

  1. Limiting reactant: NaHCO3\text{NaHCO}_3.
  2. Mass of CO2\text{CO}_2 formed: 157.08g157.08 \, \text{g}.
  3. Mass of excess reactant remaining: 71.04g71.04 \, \text{g}.

Would you like detailed step-by-step explanations for any of these calculations?


Expanding Questions:

  1. How do stoichiometric coefficients in a reaction affect limiting reactant determination?
  2. Why is it important to identify the limiting reactant in chemical reactions?
  3. How would the results differ if H3C6H5O7\text{H}_3\text{C}_6\text{H}_5\text{O}_7 was the limiting reactant instead?
  4. What are practical applications of this type of stoichiometric analysis?
  5. Can the reaction yield be affected by factors other than the limiting reactant, such as reaction conditions?

Tip: Always double-check molar masses and stoichiometric ratios when performing chemical calculations to avoid errors.

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Math Problem Analysis

Mathematical Concepts

Stoichiometry
Limiting Reactant
Molar Mass
Mass-Mole Conversions

Formulas

Moles = Mass / Molar Mass
Limiting Reactant: Compare mole ratios from the balanced equation
Mass of product = Moles of product * Molar Mass of product

Theorems

Law of Conservation of Mass
Stoichiometric Ratios

Suitable Grade Level

Grades 10-12