Math Problem Statement

Some SO3 is placed in a flask and heated to 1260 K. When equilibrium is reached, the flask is found to contain SO3 (1.32×10-2 M), SO2 (2.53×10-2 M), and O2 (4.41×10-2 M). What is the value of the equilibrium constant for the following at reaction at 1260 K?

2SO3(g) 2SO2(g) + O2(g) K =

Solution

To calculate the equilibrium constant KK for the reaction:

2SO3(g)2SO2(g)+O2(g)2 \, \text{SO}_3 (g) \rightleftharpoons 2 \, \text{SO}_2 (g) + \text{O}_2 (g)

we use the expression for the equilibrium constant in terms of concentrations:

[ K_c = \frac{[\text{SO}_2]^2 [\text{O}_2]}{[\text{SO}_3]^2} ]

Given:

  • [SO3]=1.32×102M[\text{SO}_3] = 1.32 \times 10^{-2} \, \text{M}
  • [SO2]=2.53×102M[\text{SO}_2] = 2.53 \times 10^{-2} \, \text{M}
  • [O2]=4.41×102M[\text{O}_2] = 4.41 \times 10^{-2} \, \text{M}

Now, let's calculate KcK_c by substituting these values into the formula.

Kc=(2.53×102)2×(4.41×102)(1.32×102)2K_c = \frac{(2.53 \times 10^{-2})^2 \times (4.41 \times 10^{-2})}{(1.32 \times 10^{-2})^2}

I'll compute this for you.The equilibrium constant KcK_c for the reaction at 1260 K is approximately 0.1620.162.

Would you like any further details or clarifications? Here are 5 related questions to deepen your understanding:

  1. How is the equilibrium constant affected by temperature?
  2. What is the difference between KcK_c and KpK_p in equilibrium expressions?
  3. How does Le Chatelier's Principle apply to this reaction?
  4. Why do we square the concentrations of SO2\text{SO}_2 and SO3\text{SO}_3 in the KcK_c expression?
  5. How can the equilibrium constant be used to predict the extent of a reaction?

Tip: The value of the equilibrium constant KcK_c indicates whether reactants or products are favored at equilibrium; a small value means reactants are favored, while a large value means products are favored.

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Math Problem Analysis

Mathematical Concepts

Chemical Equilibrium
Equilibrium Constants
Stoichiometry

Formulas

K_c = [SO2]^2 [O2] / [SO3]^2

Theorems

Law of Mass Action

Suitable Grade Level

Undergraduate Chemistry