Math Problem Statement

Calculate the osmolarity of a solution containing 7.5% dextrose and 0.9% sodium chloride. (M.W. of C6H14O7 = 180; M.W. of NaCl = 58.4)

Solution

To calculate the osmolarity of the solution, we need to consider the contributions of both dextrose and sodium chloride.

Step 1: Calculate the Molarity of Dextrose

  • Dextrose concentration = 7.5% (w/v), meaning 7.5 grams of dextrose in 100 mL of solution.
  • Molecular weight (M.W.) of dextrose (C₆H₁₄O₇) = 180 g/mol.

Molarity (M) of dextrose:

Molarity of dextrose=7.5 g180 g/mol×0.1 L=7.518 mol/L=0.4167 mol/L\text{Molarity of dextrose} = \frac{7.5 \text{ g}}{180 \text{ g/mol} \times 0.1 \text{ L}} = \frac{7.5}{18} \text{ mol/L} = 0.4167 \text{ mol/L}

Step 2: Calculate the Molarity of Sodium Chloride (NaCl)

  • Sodium chloride concentration = 0.9% (w/v), meaning 0.9 grams of NaCl in 100 mL of solution.
  • Molecular weight (M.W.) of NaCl = 58.4 g/mol.

Molarity (M) of sodium chloride:

Molarity of NaCl=0.9 g58.4 g/mol×0.1 L=0.95.84 mol/L=0.1541 mol/L\text{Molarity of NaCl} = \frac{0.9 \text{ g}}{58.4 \text{ g/mol} \times 0.1 \text{ L}} = \frac{0.9}{5.84} \text{ mol/L} = 0.1541 \text{ mol/L}

Step 3: Determine the Number of Particles in Solution

  • Dextrose is a non-electrolyte, so it does not dissociate in solution. Therefore, it contributes 1 particle per molecule.
  • NaCl dissociates into 2 particles (Na⁺ and Cl⁻) in solution.

Step 4: Calculate the Osmolarity

  • Osmolarity of dextrose = 0.4167 mol/L × 1 = 0.4167 osmoles/L.
  • Osmolarity of NaCl = 0.1541 mol/L × 2 = 0.3082 osmoles/L.

Step 5: Add the Osmolarities

Total osmolarity=0.4167 osmoles/L+0.3082 osmoles/L=0.7249 osmoles/L\text{Total osmolarity} = 0.4167 \text{ osmoles/L} + 0.3082 \text{ osmoles/L} = 0.7249 \text{ osmoles/L}

Thus, the osmolarity of the solution is approximately 0.725 osmoles/L.

Would you like further details or have any other questions?


Here are some related questions:

  1. How does osmolarity differ from osmolality?
  2. What are the effects of osmolarity on cellular function?
  3. How do you calculate the osmolarity of a solution with multiple electrolytes?
  4. Why does sodium chloride dissociate into two particles in solution?
  5. What is the significance of molecular weight in calculating osmolarity?

Tip: Always double-check the dissociation of compounds when calculating osmolarity, as different solutes may dissociate differently in solution.

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Math Problem Analysis

Mathematical Concepts

Osmolarity
Molarity
Concentration calculations

Formulas

Molarity (M) = (mass of solute in g) / (molar mass in g/mol × volume of solution in L)
Osmolarity = Molarity × Number of particles per molecule

Theorems

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Suitable Grade Level

Undergraduate (College Level Chemistry or Biology)