Math Problem Statement

The lattice constant of a crystal is 0.5. Calculate the maximum possible Bragg angle (degrees) for X-ray diffraction with a wavelength of 0.15 nm

Solution

To calculate the maximum possible Bragg angle for X-ray diffraction, we use Bragg's Law:

nλ=2dsinθn \lambda = 2d \sin \theta

Where:

  • nn is the order of diffraction (we typically take n=1n = 1 for the first order),
  • λ\lambda is the wavelength of the X-rays (given as 0.15nm0.15 \, \text{nm}),
  • dd is the interplanar spacing, which for a cubic crystal is related to the lattice constant aa by d=a2d = \frac{a}{2},
  • θ\theta is the Bragg angle.

We are tasked with finding the maximum Bragg angle, which occurs when sinθ=1\sin \theta = 1, or θ=90\theta = 90^\circ.

Step-by-step calculation:

  1. The lattice constant is a=0.5nma = 0.5 \, \text{nm}.
  2. The interplanar spacing d=a2=0.52=0.25nmd = \frac{a}{2} = \frac{0.5}{2} = 0.25 \, \text{nm}.
  3. Bragg's Law simplifies to:

nλ=2dsinθn \lambda = 2d \sin \theta

For n=1n = 1 (first-order diffraction), and solving for θ\theta:

sinθ=nλ2d\sin \theta = \frac{n \lambda}{2d}

sinθ=0.152×0.25=0.3\sin \theta = \frac{0.15}{2 \times 0.25} = 0.3

θ=arcsin(0.3)\theta = \arcsin(0.3).

Now let's compute θ\theta.The maximum possible Bragg angle for X-ray diffraction is approximately 17.4617.46^\circ.

Would you like more details on the steps, or do you have any other questions?

Here are five related questions to consider:

  1. How would the Bragg angle change if the wavelength of the X-rays were increased?
  2. What effect does increasing the lattice constant have on the Bragg angle?
  3. How does the order of diffraction (nn) influence the Bragg angle?
  4. Can the Bragg angle exceed 90 degrees, and if not, why?
  5. What happens if the interplanar spacing is much smaller than the wavelength?

Tip: Always ensure the value of sinθ\sin \theta is between -1 and 1 when applying Bragg’s law, as this ensures a valid physical solution for the angle.

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Math Problem Analysis

Mathematical Concepts

Crystallography
X-ray Diffraction
Trigonometry

Formulas

Bragg's Law: nλ = 2d sinθ
Interplanar spacing for cubic crystals: d = a/2
Sine function: sinθ = opposite/hypotenuse

Theorems

Bragg's Law

Suitable Grade Level

College/University (Physics or Materials Science)