Math Problem Statement

Buckminsterfullerene (Buckyballs) have a diameter of~Inm and a molar mass of~0.7207kg/mol. Approximately what velocity must a single Buckyball be travelling at to have a de Broglie wave length larger than its diameter?

Solution

To find the velocity at which a single Buckminsterfullerene (Buckyball) must be traveling to have a de Broglie wavelength larger than its diameter, we can use the de Broglie wavelength equation:

λ=hmv\lambda = \frac{h}{mv}

Where:

  • λ\lambda is the de Broglie wavelength,
  • hh is Planck's constant (6.626×10346.626 \times 10^{-34} J·s),
  • mm is the mass of the particle,
  • vv is the velocity of the particle.

We are given:

  • The diameter of the Buckyball (dd) = 1 nm = 1×1091 \times 10^{-9} m.
  • The molar mass of the Buckyball = 0.7207 kg/mol.

To calculate the velocity, we will proceed as follows:

Step 1: Convert the molar mass to the mass of a single Buckyball.

The mass of one mole of Buckyballs is 0.7207 kg. To find the mass of a single Buckyball, we divide by Avogadro's number (NA=6.022×1023N_A = 6.022 \times 10^{23}):

m=0.72076.022×1023kgm = \frac{0.7207}{6.022 \times 10^{23}} \, \text{kg}

m1.197×1024kgm \approx 1.197 \times 10^{-24} \, \text{kg}

Step 2: Use the de Broglie equation.

To have a wavelength larger than the diameter, we want λd\lambda \geq d. Setting λ=d=1×109\lambda = d = 1 \times 10^{-9} m, we substitute into the de Broglie equation and solve for vv:

1×109=6.626×1034(1.197×1024)v1 \times 10^{-9} = \frac{6.626 \times 10^{-34}}{(1.197 \times 10^{-24})v}

Step 3: Solve for vv.

Rearranging to solve for vv:

v=6.626×1034(1.197×1024)(1×109)v = \frac{6.626 \times 10^{-34}}{(1.197 \times 10^{-24})(1 \times 10^{-9})}

v5.54m/sv \approx 5.54 \, \text{m/s}

Conclusion:

The velocity at which a single Buckyball must be traveling to have a de Broglie wavelength larger than its diameter is approximately 5.54 m/s.

Would you like more details or have any questions?

Related Questions:

  1. How does the velocity change if the diameter of the particle is doubled?
  2. What is the de Broglie wavelength for a particle moving at 10 m/s?
  3. How does increasing the mass of a particle affect its de Broglie wavelength?
  4. Can the de Broglie wavelength of macroscopic objects be observed?
  5. How would the velocity change if the molar mass were increased to 1 kg/mol?

Tip:

De Broglie wavelengths are only significant for very small particles; for macroscopic objects, the wavelengths are typically too small to observe.

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Math Problem Analysis

Mathematical Concepts

Quantum Mechanics
Wave-Particle Duality
De Broglie Wavelength

Formulas

De Broglie wavelength equation: λ = h / mv
Mass conversion using Avogadro's number: m = M / N_A

Theorems

De Broglie's Hypothesis

Suitable Grade Level

Undergraduate Physics