Math Problem Statement

If a silver nitrate solution is added to excess sodium sulfide, this reaction takes place: 2AgNO3(aq) + Na2S(aq) → Ag2S(s) + 2NaNO3(aq).

Suppose you use 0.0150 liter of a 2.50 M solution of silver nitrate. Assuming the reaction goes to completion, how much silver sulfide is produced? Use the periodic table.

A. 1.49 g B. 4.65 g C. 9.30 g D. 18.6 g

Solution

To solve this, we'll need to calculate the amount of silver sulfide (Ag₂S) produced based on the given quantities.

Step 1: Calculate the moles of silver nitrate (AgNO₃)

We are given:

  • Volume of AgNO₃ solution = 0.0150 L
  • Molarity of AgNO₃ solution = 2.50 M (mol/L)

The number of moles of AgNO₃ is given by the formula: moles of AgNO₃=molarity×volume (in L)\text{moles of AgNO₃} = \text{molarity} \times \text{volume (in L)} moles of AgNO₃=2.50mol/L×0.0150L=0.0375mol\text{moles of AgNO₃} = 2.50 \, \text{mol/L} \times 0.0150 \, \text{L} = 0.0375 \, \text{mol}

Step 2: Use the stoichiometry of the reaction to find moles of Ag₂S

From the balanced chemical equation: 2AgNO₃(aq)+Na₂S(aq)Ag₂S(s)+2NaNO₃(aq)2 \, \text{AgNO₃} (aq) + \text{Na₂S} (aq) \rightarrow \text{Ag₂S} (s) + 2 \, \text{NaNO₃} (aq) From the equation, 2 moles of AgNO₃ react to produce 1 mole of Ag₂S. Thus, the moles of Ag₂S produced are: moles of Ag₂S=moles of AgNO₃2=0.0375mol2=0.01875mol\text{moles of Ag₂S} = \frac{\text{moles of AgNO₃}}{2} = \frac{0.0375 \, \text{mol}}{2} = 0.01875 \, \text{mol}

Step 3: Calculate the mass of silver sulfide (Ag₂S)

Next, we need to find the molar mass of Ag₂S. Using the atomic masses from the periodic table:

  • Silver (Ag) = 107.87 g/mol
  • Sulfur (S) = 32.07 g/mol

The molar mass of Ag₂S is: molar mass of Ag₂S=2×107.87g/mol+32.07g/mol=247.81g/mol\text{molar mass of Ag₂S} = 2 \times 107.87 \, \text{g/mol} + 32.07 \, \text{g/mol} = 247.81 \, \text{g/mol}

Now, we can calculate the mass of Ag₂S produced: mass of Ag₂S=moles of Ag₂S×molar mass of Ag₂S\text{mass of Ag₂S} = \text{moles of Ag₂S} \times \text{molar mass of Ag₂S} mass of Ag₂S=0.01875mol×247.81g/mol=4.65g\text{mass of Ag₂S} = 0.01875 \, \text{mol} \times 247.81 \, \text{g/mol} = 4.65 \, \text{g}

Final Answer:

The amount of silver sulfide produced is 4.65 g, which corresponds to option B.


Would you like further details or have any questions?

Related Questions:

  1. How would the amount of silver sulfide change if a different volume of AgNO₃ solution were used?
  2. What would happen if the sodium sulfide (Na₂S) were in excess?
  3. How could you determine the limiting reagent if you were given excess AgNO₃?
  4. How do you calculate the molarity of a solution from the mass and volume of solute?
  5. What are some real-world applications of silver sulfide in chemistry?

Tip: Always check if a reactant is in excess, as this will help simplify stoichiometric calculations.

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Math Problem Analysis

Mathematical Concepts

Stoichiometry
Molarity
Chemical Reactions
Mass Calculation

Formulas

moles = molarity × volume
moles of Ag₂S = moles of AgNO₃ / 2
mass = moles × molar mass

Theorems

Law of Conservation of Mass
Stoichiometry of Chemical Reactions

Suitable Grade Level

Grades 10-12