Math Problem Statement

At 25 degrees celsius only 0.0390 mol of generric salt AB3 is soluable in 1.00L of water. what is the ksp of the salt at 25 degrees celsius. use standard notation for answer. AB3(s)<->A3+(aq)+3B-(aq)

Solution

To determine the solubility product constant KspK_{sp} for the salt AB3\text{AB}_3 at 25°C, let's analyze the given dataTo determine the solubility product constant KspK_{sp} for the salt AB3\text{AB}_3 at 25°C, let's analyze the given

  1. Given solubility: Only 0.0390 mol of AB3\text{AB}_3 is soluble in 1.00 L of water at 25°C.

    • Therefore, the molar solubility ss of AB3\text{AB}_3 is 0.0390 M.
  2. Dissociation of AB3\text{AB}_3: AB3(s)A3+(aq)+3B(aq)\text{AB}_3(s) \leftrightarrow \text{A}^{3+}(aq) + 3\text{B}^-(aq)

    For each mole of AB3\text{AB}_3 that dissolves, it produces 1 mole of A3+\text{A}^{3+} ions and 3 moles of B\text{B}^- ions.

  3. Ion concentrations in terms of solubility:

    • The concentration of A3+\text{A}^{3+} ions will be s=0.0390s = 0.0390 M.
    • The concentration of B\text{B}^- ions will be 3s=3×0.0390=0.1173s = 3 \times 0.0390 = 0.117 M.
  4. Write the KspK_{sp} expression: [ K_{sp} = [\text{A}^{3+}][\text{B}^-]^3 ]

  5. Substitute the values: Ksp=(0.0390)(0.117)3K_{sp} = (0.0390)(0.117)^3

  6. Calculate KspK_{sp}: Ksp=(0.0390)(0.00160329)6.25×105K_{sp} = (0.0390)(0.00160329) \approx 6.25 \times 10^{-5}

Answer: The solubility product constant is: Ksp=6.25×105K_{sp} = 6.25 \times 10^{-5}

Would you like further details, or have any questions?

Related Questions

  1. What would happen to KspK_{sp} if the temperature were increased?
  2. How does the KspK_{sp} expression change if AB3\text{AB}_3 dissociates into different ion ratios?
  3. How would the solubility change if common ions are added to the solution?
  4. What units are used for KspK_{sp}, and why is it unitless in this case?
  5. How is KspK_{sp} useful in predicting precipitation reactions?

Tip

Remember, KspK_{sp} is constant at a given temperature, and changes only with temperature adjustments.

Ask a new question for Free

By Image

Drop file here or Click Here to upload

Math Problem Analysis

Mathematical Concepts

Chemical Equilibrium
Solubility Product Constant (Ksp)
Stoichiometry

Formulas

Ksp = [A^(3+)][B^-]^3
Concentration of ions: [A^(3+)] = s, [B^-] = 3s
Ksp calculation: Ksp = (0.0390)(0.117)^3

Theorems

Equilibrium Theory
Law of Mass Action

Suitable Grade Level

High School (Grades 10-12) / Early College