Math Problem Statement

The average speed of a gas molecule in meters per second is v avg = root(8RT/piM), where the temperature T is given in kelvins, the molar mass M is given in kilogram--moles, and R = 8.31. Calculate dv avg / dT at T=350 K for oxygen, which has a molar mass of 0.032 kg/mol. Use decimal notation, give your answer to four decimal places.

d/dT v avg = ? m/(s⋅K)

Solution

The given formula for the average speed vavgv_{\text{avg}} of a gas molecule is:

vavg=8RTπMv_{\text{avg}} = \sqrt{\frac{8RT}{\pi M}}

Where:

  • R=8.31J/(mol\cdotpK)R = 8.31 \, \text{J/(mol·K)} (gas constant),
  • TT is the temperature in kelvins,
  • MM is the molar mass in kg/mol,
  • π\pi is the mathematical constant (approximately 3.14163.1416).

We are tasked with finding ddTvavg\frac{d}{dT}v_{\text{avg}}, the derivative of vavgv_{\text{avg}} with respect to temperature TT.

Step 1: Differentiate vavgv_{\text{avg}} with respect to TT

The function vavg=8RTπMv_{\text{avg}} = \sqrt{\frac{8RT}{\pi M}} can be rewritten as:

vavg=(8RπM)1/2T1/2v_{\text{avg}} = \left( \frac{8R}{\pi M} \right)^{1/2} T^{1/2}

Now, take the derivative of vavgv_{\text{avg}} with respect to TT:

ddTvavg=12(8RπM)1/2T1/2\frac{d}{dT} v_{\text{avg}} = \frac{1}{2} \left( \frac{8R}{\pi M} \right)^{1/2} T^{-1/2}

Step 2: Substitute known values

Given:

  • T=350KT = 350 \, \text{K},
  • R=8.31J/(mol\cdotpK)R = 8.31 \, \text{J/(mol·K)},
  • M=0.032kg/molM = 0.032 \, \text{kg/mol},
  • π=3.1416\pi = 3.1416.

Substituting these values into the derivative expression:

ddTvavg=12(8×8.313.1416×0.032)1/23501/2\frac{d}{dT} v_{\text{avg}} = \frac{1}{2} \left( \frac{8 \times 8.31}{3.1416 \times 0.032} \right)^{1/2} \cdot 350^{-1/2}

Let's calculate this step by step.The derivative of the average speed vavgv_{\text{avg}} with respect to temperature TT at T=350KT = 350 \, \text{K} for oxygen is approximately:

ddTvavg=0.6873m/(s\cdotpK)\frac{d}{dT} v_{\text{avg}} = 0.6873 \, \text{m/(s·K)}

Would you like any further details or clarifications?

Here are 5 related questions to expand on this topic:

  1. How does the molar mass affect the average speed of a gas molecule?
  2. What is the physical significance of the derivative ddTvavg\frac{d}{dT} v_{\text{avg}}?
  3. How does the average speed change if the temperature is doubled?
  4. Can this formula be applied to real gases, or is it specific to ideal gases?
  5. How does this average speed formula relate to the kinetic theory of gases?

Tip: When differentiating a square root function, express it as a fractional power for easier calculation.

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Math Problem Analysis

Mathematical Concepts

Calculus
Differentiation
Physics (Thermodynamics)

Formulas

v_avg = √(8RT / πM)
d(v_avg) / dT = (1/2) * (8R / πM)^(1/2) * T^(-1/2)

Theorems

Power Rule for Differentiation

Suitable Grade Level

Undergraduate (Calculus and Thermodynamics)