Math Problem Statement

Write an equation that gives the overall equilibrium constant K in terms of the equilibrium constants K1 and K2 for the given reactions in the image.

Solution

The problem in your image relates to calculating the overall equilibrium constant KK for the combined reactions given their individual equilibrium constants K1K_1 and K2K_2.

The reactions provided are:

  1. 2C(s)+O2(g)2CO(g)2C(s) + O_2(g) \rightleftharpoons 2CO(g) with equilibrium constant K1K_1,
  2. Fe2O3(s)+3CO(g)2Fe(s)+3CO2(g)\text{Fe}_2O_3(s) + 3CO(g) \rightleftharpoons 2Fe(s) + 3CO_2(g) with equilibrium constant K2K_2.

The net reaction is:

2Fe2O3(s)+6C(s)+3O2(g)4Fe(s)+6CO2(g)2 \text{Fe}_2O_3(s) + 6C(s) + 3O_2(g) \rightleftharpoons 4Fe(s) + 6CO_2(g)

To find the overall equilibrium constant KK, we need to combine the constants K1K_1 and K2K_2. Since the second reaction involves 3 moles of CO, we will need to cube the equilibrium constant K1K_1 to account for that.

Here’s how the combination works:

  • The first reaction is doubled (because we need 6 moles of CO), so the new equilibrium constant becomes K13K_1^3 (since the equilibrium constant is raised to the power of the stoichiometric coefficient).
  • The second reaction remains unchanged, with equilibrium constant K2K_2.

Now, we multiply the equilibrium constants to get the overall equilibrium constant:

K=K13×K2K = K_1^3 \times K_2

So, the final expression for KK is:

K=K13×K2K = K_1^3 \times K_2

Would you like more details on how this combination works or have any further questions?

Here are 5 related questions to further expand your understanding:

  1. What is the physical significance of equilibrium constants in chemical reactions?
  2. How do changes in reaction conditions affect the equilibrium constant?
  3. Why is it necessary to cube K1K_1 in this reaction, and what does it represent?
  4. Can equilibrium constants be used to predict the direction of a reaction?
  5. How are equilibrium constants related to Gibbs free energy in a reaction?

Tip: Remember, when combining equilibrium constants from sequential reactions, the overall constant is the product of the individual constants, adjusting for any changes in the stoichiometry.

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Math Problem Analysis

Mathematical Concepts

Chemistry
Equilibrium Constants
Stoichiometry

Formulas

K = K1^3 × K2

Theorems

Law of Mass Action

Suitable Grade Level

Grades 11-12 (High School Chemistry)