Math Problem Statement

Calculate ΔG° (in kJ/mol) for each of the following reactions from the equilibrium constant at the temperature given. (a) N2(g) + 2 O2(g) equilibrium reaction arrow 2 NO2(g) T = 840.°C K = 3.3 ✕ 10−10 ΔG° =

Solution

The standard Gibbs free energy change (ΔG\Delta G^\circ) for a reaction can be calculated using the following formula:

ΔG=RTlnK\Delta G^\circ = -RT \ln K

where:

  • RR is the gas constant, which is 8.314Jmol1K18.314 \, \text{J} \cdot \text{mol}^{-1} \cdot \text{K}^{-1},
  • TT is the temperature in Kelvin (KK),
  • KK is the equilibrium constant.

Step 1: Convert Temperature to Kelvin

Given T=840CT = 840^\circ C: T=840+273.15=1113.15KT = 840 + 273.15 = 1113.15 \, K

Step 2: Substitute the Values

  • R=8.314Jmol1K1R = 8.314 \, \text{J} \cdot \text{mol}^{-1} \cdot \text{K}^{-1},
  • T=1113.15KT = 1113.15 \, K,
  • K=3.3×1010K = 3.3 \times 10^{-10}.

Step 3: Calculate ΔG\Delta G^\circ

ΔG=(8.314)(1113.15)ln(3.3×1010)\Delta G^\circ = - (8.314) (1113.15) \ln (3.3 \times 10^{-10})

Now let's compute this numerically:

ln(3.3×1010)21.83\ln (3.3 \times 10^{-10}) \approx -21.83

ΔG(8.314)(1113.15)(21.83)202277.4J/mol=202.3kJ/mol\Delta G^\circ \approx - (8.314) (1113.15) (-21.83) \approx 202277.4 \, \text{J/mol} = 202.3 \, \text{kJ/mol}

Final Answer:

ΔG202.3kJ/mol\Delta G^\circ \approx 202.3 \, \text{kJ/mol}

Would you like further details or have any questions? Here are some related questions to explore:

  1. How does a change in temperature affect the value of ΔG\Delta G^\circ?
  2. What happens to ΔG\Delta G^\circ if KK is increased?
  3. What is the physical significance of a positive or negative ΔG\Delta G^\circ?
  4. How does ΔG\Delta G^\circ relate to the spontaneity of a reaction?
  5. What other thermodynamic parameters can be used to describe chemical reactions?

Tip: Always ensure the temperature is in Kelvin when using thermodynamic equations like ΔG=RTlnK\Delta G^\circ = -RT \ln K.

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Math Problem Analysis

Mathematical Concepts

Thermodynamics
Gibbs Free Energy
Logarithmic Calculations

Formulas

ΔG° = -RT ln K

Theorems

Gibbs Free Energy and Equilibrium Constant Relationship

Suitable Grade Level

Undergraduate Chemistry