Math Problem Statement
Calculate ΔG° (in kJ/mol) for each of the following reactions from the equilibrium constant at the temperature given. (a) N2(g) + 2 O2(g) equilibrium reaction arrow 2 NO2(g) T = 840.°C K = 3.3 ✕ 10−10 ΔG° =
Solution
The standard Gibbs free energy change () for a reaction can be calculated using the following formula:
where:
- is the gas constant, which is ,
- is the temperature in Kelvin (),
- is the equilibrium constant.
Step 1: Convert Temperature to Kelvin
Given :
Step 2: Substitute the Values
- ,
- ,
- .
Step 3: Calculate
Now let's compute this numerically:
Final Answer:
Would you like further details or have any questions? Here are some related questions to explore:
- How does a change in temperature affect the value of ?
- What happens to if is increased?
- What is the physical significance of a positive or negative ?
- How does relate to the spontaneity of a reaction?
- What other thermodynamic parameters can be used to describe chemical reactions?
Tip: Always ensure the temperature is in Kelvin when using thermodynamic equations like .
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Math Problem Analysis
Mathematical Concepts
Thermodynamics
Gibbs Free Energy
Logarithmic Calculations
Formulas
ΔG° = -RT ln K
Theorems
Gibbs Free Energy and Equilibrium Constant Relationship
Suitable Grade Level
Undergraduate Chemistry
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