Math Problem Statement

For the following reaction, Kp = 0.643 at a given temperature. C(s) + 2H2(g) equilibrium reaction arrow CH4(g) At equilibrium, PCH4 = 6.73. What is the equilibrium partial pressure of H2?

Solution

We are given the reaction:

C(s)+2H2(g)CH4(g)\text{C(s)} + 2\text{H}_2(g) \rightleftharpoons \text{CH}_4(g)

with an equilibrium constant Kp=0.643K_p = 0.643 and the equilibrium partial pressure of methane, PCH4=6.73atmP_{\text{CH}_4} = 6.73 \, \text{atm}. We need to find the equilibrium partial pressure of hydrogen, PH2P_{\text{H}_2}.

The equilibrium expression for the reaction is given by:

Kp=PCH4PH22K_p = \frac{P_{\text{CH}_4}}{P_{\text{H}_2}^2}

Substitute the known values into the equation:

0.643=6.73PH220.643 = \frac{6.73}{P_{\text{H}_2}^2}

Now, solve for PH2P_{\text{H}_2}:

PH22=6.730.643P_{\text{H}_2}^2 = \frac{6.73}{0.643}

PH22=10.466P_{\text{H}_2}^2 = 10.466

Take the square root of both sides:

PH2=10.466P_{\text{H}_2} = \sqrt{10.466}

PH23.24atmP_{\text{H}_2} \approx 3.24 \, \text{atm}

So, the equilibrium partial pressure of H2\text{H}_2 is approximately 3.24atm3.24 \, \text{atm}.


Would you like any further details or clarifications?

Here are 5 related questions to expand your understanding:

  1. How does the value of KpK_p change with temperature?
  2. What would happen to the equilibrium if more hydrogen gas was added?
  3. How is KpK_p related to KcK_c for this reaction?
  4. Why is the pressure of solid carbon not included in the equilibrium expression?
  5. How would the equilibrium shift if the volume of the container was decreased?

Tip: Always remember to check the units of pressure and ensure they are consistent with the equilibrium constant KpK_p used in your calculations.

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Math Problem Analysis

Mathematical Concepts

Chemical Equilibrium
Algebraic Manipulation
Equilibrium Constants

Formulas

Kp = P_CH4 / P_H2^2
P_H2^2 = P_CH4 / Kp
P_H2 = sqrt(P_H2^2)

Theorems

Equilibrium Constant Expression

Suitable Grade Level

Grades 10-12