Math Problem Statement

The lattice parameter and atomic mass of a diamond crystal are 3.57 A and 12 respectively. Calculate the density of diamond. Number of atoms per unit cell is 8 for diamond

Solution

To calculate the density of a diamond crystal, we'll use the following formula:

Density(ρ)=Z×Ma3×NA\text{Density} (\rho) = \frac{Z \times M}{a^3 \times N_A}

where:

  • ZZ is the number of atoms per unit cell (which is 8 for diamond),
  • MM is the atomic mass of carbon (which is 12 amu),
  • aa is the lattice parameter (which is 3.57 Å),
  • NAN_A is Avogadro's number (6.022×10236.022 \times 10^{23} atoms/mol).

First, let's convert the lattice parameter from angstroms to centimeters:

a=3.57 A˚=3.57×108 cma = 3.57 \text{ Å} = 3.57 \times 10^{-8} \text{ cm}

Now we can calculate the density:

ρ=8×12 g/mol(3.57×108 cm)3×6.022×1023 atoms/mol\rho = \frac{8 \times 12 \text{ g/mol}}{(3.57 \times 10^{-8} \text{ cm})^3 \times 6.022 \times 10^{23} \text{ atoms/mol}}

Let's compute this step by step.

Step 1: Calculate the volume of the unit cell

a3=(3.57×108 cm)3=4.546×1023 cm3a^3 = (3.57 \times 10^{-8} \text{ cm})^3 = 4.546 \times 10^{-23} \text{ cm}^3

Step 2: Calculate the density

ρ=96 g/mol4.546×1023 cm3×6.022×1023 atoms/mol\rho = \frac{96 \text{ g/mol}}{4.546 \times 10^{-23} \text{ cm}^3 \times 6.022 \times 10^{23} \text{ atoms/mol}}

ρ=96 g/mol2.737×101 g/mol cm3\rho = \frac{96 \text{ g/mol}}{2.737 \times 10^{1} \text{ g/mol cm}^3}

ρ=3.51 g/cm3\rho = 3.51 \text{ g/cm}^3

So, the density of diamond is approximately 3.51 g/cm33.51 \text{ g/cm}^3.

Would you like more details or have any questions?


Here are 5 related questions:

  1. How does the density of diamond compare to other allotropes of carbon?
  2. What factors affect the lattice parameter of a crystal structure?
  3. Can you calculate the density of another crystal using the same method?
  4. How does temperature affect the density of diamond?
  5. How is Avogadro's number determined experimentally?

Tip: Always ensure units are consistent when calculating physical quantities like density.

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Math Problem Analysis

Mathematical Concepts

Crystallography
Density Calculations

Formulas

Density formula: ρ = Z × M / (a^3 × NA)

Theorems

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Suitable Grade Level

Undergraduate Level