Math Problem Statement

The specific heat of argon at constant pressure and constant volume are Cp and Cy respectively. It's density ‘p' at N.T.P. will be

[P and T are pressure and temperature respectively at N.T.P.]

Solution

The density of argon (pp) at normal temperature and pressure (N.T.P.) can be found using the ideal gas law:

pV=nRTpV = nRT

Rearranging to express density in terms of known quantities at N.T.P.:

  1. Write the ideal gas law in terms of molar mass and density:

    PV=nRTP=nRTVp=MV=PMRTPV = nRT \Rightarrow P = \frac{nRT}{V} \Rightarrow p = \frac{M}{V} = \frac{PM}{RT}

    Here:

    • pp is the density,
    • MM is the molar mass of argon,
    • RR is the gas constant, and
    • TT is the temperature at N.T.P.
  2. Use the relationship between CpC_p and CvC_v for an ideal gas:

    For an ideal gas, the ratio γ=CpCv\gamma = \frac{C_p}{C_v} is used to relate CpC_p and CvC_v.

  3. Substitute into the density formula:

    Since we know the values at N.T.P. (where PP and TT are constants):

    p=PMRTp = \frac{P \cdot M}{R \cdot T}

  4. Final density expression:

    By substituting the known molar mass for argon and constants PP and TT at N.T.P., you would arrive at a numerical answer for pp.

This density calculation assumes you have values for CpC_p and CvC_v, which relate to the molar mass and specific heat ratio. Would you like the step-by-step computation with specific values?


  1. How does the ideal gas law apply to other noble gases like helium?
  2. What role does molar mass play in calculating gas density?
  3. How can specific heats CpC_p and CvC_v help in understanding gas behavior under different conditions?
  4. What are typical values of CpC_p and CvC_v for argon, and how do they affect density?
  5. How would this calculation change at a different temperature or pressure?

Tip: When using the ideal gas law, remember that it assumes ideal conditions, so deviations can occur at very high pressures or low temperatures.

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Math Problem Analysis

Mathematical Concepts

Ideal Gas Law
Density
Specific Heat
Thermodynamics

Formulas

Ideal gas law: pV = nRT
Density formula: p = PM / RT
Relationship of specific heats for ideal gases: γ = Cp/Cv

Theorems

Ideal Gas Law
Relationship between Cp and Cv for ideal gases

Suitable Grade Level

Undergraduate Physics or Chemistry