Math Problem Statement

The synthesis of ammonia proceeds according to the following reaction: N₂ + 3 H₂ → 2 NH₃. In a given plant, 4202 lb of nitrogen and 1046 lb of hydrogen are fed to the synthesis reactor per hour. Production of pure ammonia from this reactor is 3060 lb per hour. Calculate: (a) the limiting reactant, (b) the percent excess reactant, and (c) the percent conversion obtained based on the limiting reactant.

Solution

To solve this problem, we will address each part (a, b, and c) individually using stoichiometry and relevant chemical principles.

Given Data and Reaction

Reaction: N2+3H22NH3\text{N}_2 + 3\text{H}_2 \rightarrow 2\text{NH}_3

Data provided:

  • Nitrogen (N₂): 4202 lb per hour
  • Hydrogen (H₂): 1046 lb per hour
  • Ammonia (NH₃) produced: 3060 lb per hour

Molar Masses

  • Molar mass of N₂: 28g/mol28 \, \text{g/mol}
  • Molar mass of H₂: 2g/mol2 \, \text{g/mol}
  • Molar mass of NH₃: 17g/mol17 \, \text{g/mol}

Step 1: Convert Given Masses to Moles

  1. Convert nitrogen (N₂) to moles: Moles of N2=4202lb×453.592g/lb28g/mol\text{Moles of N}_2 = \frac{4202 \, \text{lb} \times 453.592 \, \text{g/lb}}{28 \, \text{g/mol}}

  2. Convert hydrogen (H₂) to moles: Moles of H2=1046lb×453.592g/lb2g/mol\text{Moles of H}_2 = \frac{1046 \, \text{lb} \times 453.592 \, \text{g/lb}}{2 \, \text{g/mol}}

Step 2: Determine the Limiting Reactant

From the reaction, 1 mole of N₂ reacts with 3 moles of H₂ to produce 2 moles of NH₃. We’ll use the mole ratios and calculated moles to find the limiting reactant.

Step 3: Calculate Percent Excess Reactant

Using the limiting reactant, we can determine how much of the other reactant is in excess and then calculate the percent excess.

Step 4: Calculate Percent Conversion (Based on Limiting Reactant)

Percent conversion will be based on the actual yield (3060 lb of NH₃ produced) compared to the theoretical yield calculated from the limiting reactant.


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Follow-Up Questions

  1. What is the purpose of identifying the limiting reactant in a reaction?
  2. How does calculating the percent excess help in optimizing chemical reactions?
  3. Why is it necessary to calculate theoretical yield before determining percent conversion?
  4. How would the calculations change if the reactor efficiency were considered?
  5. Can this method be applied to other types of reactions with different stoichiometries?

Tip

When working with stoichiometry, always start by balancing the equation and identifying molar masses for accurate conversions.

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Math Problem Analysis

Mathematical Concepts

Stoichiometry
Limiting Reactant
Percent Excess
Percent Conversion

Formulas

Moles = mass / molar mass
Limiting Reactant determination using mole ratio
Percent Excess = ((amount of excess reactant used - required amount) / required amount) * 100
Percent Conversion = (actual yield / theoretical yield) * 100

Theorems

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Suitable Grade Level

Grades 11-12