Math Problem Statement
Calculate the change in entropy accompanying isothermal expansion of 5 moles of ideal gas at 330K until is volume raised to 6 times of its initial.
Solution
The change in entropy () for the isothermal expansion of an ideal gas can be calculated using the formula:
where:
- is the number of moles of the gas,
- is the universal gas constant (8.314 J/(mol·K)),
- is the final volume,
- is the initial volume.
Since the final volume is 6 times the initial volume , we have .
Given dataThe change in entropy () for the isothermal expansion of an ideal gas can be calculated using the formula:
where:
- is the number of moles of the gas,
- is the universal gas constant (8.314 J/(mol·K)),
- is the final volume,
- is the initial volume.
Since the final volume is 6 times the initial volume , we have .
Given
- moles,
- (though temperature doesn’t directly affect here as it’s only in the formula implicitly through the gas constant),
- .
Now, substituting values:
Calculating each part:
-
Calculate :
-
Substitute into the equation:
-
Solving:
Answer:
The change in entropy, , is approximately 74.5 J/K.
Would you like further details on the derivation of this formula or any additional steps?
- How does temperature affect the entropy change in an isothermal process?
- What would the entropy change be if the volume increased by a different factor?
- How does entropy change during an isothermal compression compared to expansion?
- How is entropy calculated for non-ideal gases?
- What are practical implications of entropy change in thermodynamic cycles?
Tip: Always check if the process is reversible; entropy change formulas often assume reversibility.
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Math Problem Analysis
Mathematical Concepts
Thermodynamics
Entropy
Logarithmic Functions
Formulas
ΔS = nR ln(Vf/Vi)
Theorems
Second Law of Thermodynamics
Suitable Grade Level
Grades 11-12