Math Problem Statement

Calculate the change in entropy accompanying isothermal expansion of 5 moles of ideal gas at 330K until is volume raised to 6 times of its initial.

Solution

The change in entropy (ΔS\Delta S) for the isothermal expansion of an ideal gas can be calculated using the formula:

ΔS=nRlnVfVi\Delta S = nR \ln \frac{V_f}{V_i}

where:

  • nn is the number of moles of the gas,
  • RR is the universal gas constant (8.314 J/(mol·K)),
  • VfV_f is the final volume,
  • ViV_i is the initial volume.

Since the final volume VfV_f is 6 times the initial volume ViV_i, we have VfVi=6\frac{V_f}{V_i} = 6.

Given dataThe change in entropy (ΔS\Delta S) for the isothermal expansion of an ideal gas can be calculated using the formula:

ΔS=nRlnVfVi\Delta S = nR \ln \frac{V_f}{V_i}

where:

  • nn is the number of moles of the gas,
  • RR is the universal gas constant (8.314 J/(mol·K)),
  • VfV_f is the final volume,
  • ViV_i is the initial volume.

Since the final volume VfV_f is 6 times the initial volume ViV_i, we have VfVi=6\frac{V_f}{V_i} = 6.

Given

  • n=5n = 5 moles,
  • T=330KT = 330 \, \text{K} (though temperature doesn’t directly affect ΔS\Delta S here as it’s only in the formula implicitly through the gas constant),
  • R=8.314J/(mol\cdotpK)R = 8.314 \, \text{J/(mol·K)}.

Now, substituting values:

ΔS=(5moles)×(8.314J/(mol\cdotpK))×ln(6)\Delta S = (5 \, \text{moles}) \times (8.314 \, \text{J/(mol·K)}) \times \ln(6)

Calculating each part:

  1. Calculate ln(6)\ln(6): ln(6)1.7918\ln(6) \approx 1.7918

  2. Substitute into the equation: ΔS=5×8.314×1.7918\Delta S = 5 \times 8.314 \times 1.7918

  3. Solving: ΔS74.5J/K\Delta S \approx 74.5 \, \text{J/K}

Answer:

The change in entropy, ΔS\Delta S, is approximately 74.5 J/K.

Would you like further details on the derivation of this formula or any additional steps?


  1. How does temperature affect the entropy change in an isothermal process?
  2. What would the entropy change be if the volume increased by a different factor?
  3. How does entropy change during an isothermal compression compared to expansion?
  4. How is entropy calculated for non-ideal gases?
  5. What are practical implications of entropy change in thermodynamic cycles?

Tip: Always check if the process is reversible; entropy change formulas often assume reversibility.

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Math Problem Analysis

Mathematical Concepts

Thermodynamics
Entropy
Logarithmic Functions

Formulas

ΔS = nR ln(Vf/Vi)

Theorems

Second Law of Thermodynamics

Suitable Grade Level

Grades 11-12