Math Problem Statement

Lithium forms compounds which are used in dry cells, storage batteries, and in high-temperature lubricants. It has two naturally occurring isotopes, 6Li (isotopic mass = 6.015123 amu) and 7Li (isotopic mass = 7.016005 amu). Lithium has an atomic mass of 6.9412 amu. What is the percent abundance of lithium-6? (Show work on your sheet).

Solution

To find the percent abundance of lithium-6, we will use the formula for the average atomic mass:

Atomic Mass=(fLi-6×mass of Li-6)+(fLi-7×mass of Li-7)\text{Atomic Mass} = (f_{\text{Li-6}} \times \text{mass of Li-6}) + (f_{\text{Li-7}} \times \text{mass of Li-7})

Where:

  • fLi-6f_{\text{Li-6}} = fraction of lithium-6 isotope
  • fLi-7=1fLi-6f_{\text{Li-7}} = 1 - f_{\text{Li-6}} (since the total abundance must equal 100%)
  • Atomic mass of lithium = 6.9412 amu
  • Mass of lithium-6 (\text{Li-6}) = 6.015123 amu
  • Mass of lithium-7 (\text{Li-7}) = 7.016005 amu

Step 1: Set up the equation

6.9412=(fLi-6×6.015123)+[(1fLi-6)×7.016005]6.9412 = (f_{\text{Li-6}} \times 6.015123) + [(1 - f_{\text{Li-6}}) \times 7.016005]

Step 2: Expand the equation

6.9412=fLi-6×6.015123+(1fLi-6)×7.0160056.9412 = f_{\text{Li-6}} \times 6.015123 + (1 - f_{\text{Li-6}}) \times 7.016005

6.9412=fLi-6×6.015123+7.016005fLi-6×7.0160056.9412 = f_{\text{Li-6}} \times 6.015123 + 7.016005 - f_{\text{Li-6}} \times 7.016005

Step 3: Combine like terms

6.9412=fLi-6×(6.0151237.016005)+7.0160056.9412 = f_{\text{Li-6}} \times (6.015123 - 7.016005) + 7.016005

6.9412=fLi-6×(1.000882)+7.0160056.9412 = f_{\text{Li-6}} \times (-1.000882) + 7.016005

Step 4: Subtract 7.016005 from both sides

6.94127.016005=fLi-6×(1.000882)6.9412 - 7.016005 = f_{\text{Li-6}} \times (-1.000882)

0.074805=fLi-6×(1.000882)-0.074805 = f_{\text{Li-6}} \times (-1.000882)

Step 5: Solve for fLi-6f_{\text{Li-6}}

fLi-6=0.0748051.000882f_{\text{Li-6}} = \frac{-0.074805}{-1.000882}

fLi-6=0.074772f_{\text{Li-6}} = 0.074772

So, the fraction of lithium-6 is approximately 0.074772.

Step 6: Convert to percentage

Percent abundance of Li-6=0.074772×100=7.48%\text{Percent abundance of Li-6} = 0.074772 \times 100 = 7.48\%

Thus, the percent abundance of lithium-6 is 7.48%.

Would you like a further breakdown of any steps?

Related Questions:

  1. What is the percent abundance of lithium-7?
  2. How does atomic mass affect the properties of elements?
  3. Why is lithium used in high-temperature lubricants?
  4. What is the difference between atomic mass and mass number?
  5. How do isotopes influence the average atomic mass of an element?

Tip:

When solving problems with multiple isotopes, always remember the total abundance sums to 100%, and isolate variables step-by-step for clarity.

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Math Problem Analysis

Mathematical Concepts

Isotopic abundance
Weighted average
Algebra

Formulas

Atomic mass = (f_Li-6 × mass of Li-6) + (f_Li-7 × mass of Li-7)
f_Li-7 = 1 - f_Li-6

Theorems

Isotopic weighted average formula

Suitable Grade Level

Grades 10-12