Math Problem Statement

Consider the the model chemical reaction A + X k1 ⇄ k−1 2X in which one molecule of X combines with one molecule of A to form two molecules of X. This means that the chemical X stimulates its own production, a process called autocatalysis. Eventually, this leads to a limitation based on the number of molecules of A. Thus there is a “back reaction” in which 2X returns to A + X. According to the law of mass action of chemical kinetics, the rate of an elementary reaction is proportional to the product of the concentrations of the reactants. We denote the concentrations by lowercase letters x = [X] and a = [A]. Assume that there’s an enormous surplus of chemical A, so that its concentration a can be regarded as constant. Then the equation for the kinetics of x is ̇x = k1ax − k−1x2 . (a) Explain in words what each term means in the context of the model of auto- catalysis. (Note: All the information you need is in the problem, you do not have to know more than that about autocatalysis.) (b) Find all the fixed points of this equation and classify their stability. (c) Sketch the graph of x(t) for various initial values x0. Interpret each trajectory by describing the behavior in the context of autocatalysis. Make sure to graph solutions!

Solution

The graph above shows the concentration of XX over time for various initial conditions x0x_0.

  • When x0=0x_0 = 0, the concentration remains zero, but this is an unstable equilibrium.
  • For small initial values (x0=0.1x_0 = 0.1, x0=0.5x_0 = 0.5), the concentration of XX increases and approaches the stable fixed point at x=k1ak1=1x = \frac{k_1 a}{k_{-1}} = 1.
  • For larger initial values (x0=2x_0 = 2), the concentration decreases towards the same stable fixed point.

The system stabilizes at x=1x = 1, demonstrating the behavior of autocatalysis where the production of XX is balanced by the back reaction limiting its growth.

Do you want further details or have any questions?

Here are some related questions to explore:

  1. How would the dynamics change if the concentration of AA were not constant?
  2. What happens to the system if k1k_1 or k1k_{-1} are increased or decreased?
  3. How would the system behave if there was a delay in the autocatalytic reaction?
  4. What is the physical interpretation of the stability of the fixed points in a real chemical system?
  5. How could you modify this model to include other possible reactions involving AA and XX?

Tip: The stability of fixed points can often be determined by considering the signs of the derivatives at those points, which gives insight into how small perturbations affect the system.

Ask a new question for Free

By Image

Drop file here or Click Here to upload

Math Problem Analysis

Mathematical Concepts

Differential Equations
Chemical Kinetics
Autocatalysis
Stability Analysis

Formulas

Rate equation: ̇x = k1ax − k−1x^2
Fixed points: k1a = k−1x^2

Theorems

Law of Mass Action
Stability of Fixed Points

Suitable Grade Level

Undergraduate (Chemistry/Applied Mathematics)